Introduction To Heat, Internal Energy And Work

We already know what heat is. It is a form of energy but it always comes into picture when energy is being transferred from one system to another. Suppose we are at an initial state ‘a’ and want to go to a final state ‘b’. We can do that by various processes (as shown in the figure) and heat energy released or absorbed in all the processes is different. So we can see that heat does not depend on the state of system.

heat & State of system

So there was a need to define another term which was dependent on the state of the system. This is termed as Internal Energy. In the next section, let us learn more about internal energy.

What is Internal Energy?

Internal energy definition is given as:

The energy contained within the system associated to random motions of the particles along with the potential energies of the molecules due to their orientation.

The energy due to random motion includes translational, rotational, and vibrational energy. It is represented as U. So now we can say since internal energy is a state function and in all the processes shown above the change in internal energy from state ‘a’ to state ‘b’ will be same.

Internal Energy Formula

Following is the formula of internal energy:

ΔU = Q + W

Where,

  • ΔU is the internal energy
  • Q is the heat added to the system
  • W is the work done by the system

Difference between Internal Energy and Enthalpy

Interval energy vs enthalpy is given below:

Internal energy Enthalpy
It is the total energy in the system It is the relationship between the system and the surrounding
The formula of internal energy is:

ΔU = Q + W

The formula of enthalpy is:

H = U + PV

Relation between Internal Energy and Enthalpy

Following derivation is the explanation for relation between internal energy and enthalpy for an ideal gas, also a mathematical way to show that the internal energy of an ideal gas is a function of temperature only.

For an ideal gas, internal energy is given as:

U = U(T)

And enthalpy is given as:

H = U + PV

Using ideal gas equation, PV = RT

H = U + RT

In the above equation, R is the universal gas constant.

Enthalpy of an ideal gas is given as:

H = H(T)

We know that specific heat at constant pressure and volume are temperature dependent can be given as:

dU = Cv (T) dT

dH = Cp (T) dT

Using above equations, specific heat ratio k is given as:

\(k= \frac{C_{p}}{C_{v}}=\frac{U}{H}\)

This is the relation between internal energy and enthalpy for an ideal gas.

Work Done by a System

Similar to the quantities heat and internal energy, there is another term known as work that is associated with the transfer of energy. Suppose a piston contains gas. If the piston moves outwards, we say work is done by the gas and it is positive. Similarly if it moves inwards, work is done on the gas and it is negative. Let’s take the following figure:

movement of piston

\(Work done\) = \(\int(F.dx)\)

= \(\int P(A.dx) \)

= \( \int P.dV \)

We can use the above equation to find work done by a gas. Also graphical approach suggests that work done is the area under P – V graph. So for the above described process we can see area is different for different processes (as shown in figure below) and hence work is also not a state function and depends on path.

work is state independent

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