Let us consider an electron that is revolving around in a circle of radius r with a velocity v. The charge of the electron is e and its mass is me both of which are constants. The time period T of the electrons orbit is:
The current \(i\)
Note that the current is in the opposite direction as the electron is negatively charged. The magnetic moment due to a current loop enclosing an area A is given by:
Magnetic moment of an electron:
Let us divide and multiply by the mass of the electron,
We know that the angular momentum \(L\)
Thus we can write,
Since the angular momentum is given by the right hand rule with respect to the velocity and the current is in the opposite direction, the negative sign shows that the two quantities are on opposing directions as shown in the figure,
This is an important result as the magnetic moment is only dependent on the angular momentum. This is why the orbital angular momentum and orbital magnetic moment terms are used interchangeably. The same is true for the spin angular moment.
For an electron revolving in an atom, the angular momentum is quantized as proposed by Niels Bohr.
The angular momentum is given by:
Where n is the orbit quantum number and h is the Planck’s constant,
The quantity that multiplies with n is a constant known as the Bohr Magneton \(μ_B\)
The Bohr Magneton is used very widely to express magnetic moments at the atomic scale.
The expression we obtained is good for only simple atoms like hydrogen and does not predict all the magnetic moment states of an electron. As you would have learnt in chemistry, the electron does not really revolve around the nucleus. Instead the electron’s orbital magnetic moment is obtained by virtue of being trapped in the nucleuses potential well.
The spin magnetic moment and orbital magnetic moment combine vectorially and the magnetic moments of atoms in a sample also combine to produce the net magnetic moment of the sample. It is these magnetic moments obtained by the combination of orbital and spin magnetic moments which determine the magnetic properties of materials.
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