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Nomenclature of Alcohols

Alcohols provides the first example of how the parent alkane was the starting point for the nomenclature of all families of compounds. The -ane suffix is modified in a systematic manner to indicate the presence of a functional group. Alcohol is named by identifying the longest straight carbon chain containing the -OH group. The -ane suffix is replaced with -anol and the location of the -OH group on the chain is designed by a number. 

The generic IUPAC name for alcohol is alkanols, and they are represented in reactions by the general formula R-OH. The presence of other substituents in alcohol is indicated by their names and numerical positions, always keeping the lowest possible number for the hydroxyl group.

Table of Contents

IUPAC Nomenclature for Alcohols

The following procedure should be followed in giving alcohol IUPAC substitutive names.

  1. Select the longest continuous chain to which the hydroxyl group is directly attached. Change the name of the alkane corresponding to the chain by dropping the final -e and adding the suffix -ol.
  2. Number the longest continuous carbon chain so as to give the carbon atom bearing the hydroxyl group the lower number. Indicate the position of the hydroxyl group by using this number as a locant.
  3. Indicate the position of another substituent as a prefix by using the numbers corresponding to their positions along the carbon chain as locants.

The following example shows how the rules are applied.

IUPAC Nomenclature for Alcohols

IUPAC Nomenclature for Alcohols

Types of Nomenclature in Alcohols

There are three systems of naming alcohols

  1. Common or trivial system 
  2. Carbinol system and 
  3. IUPAC system
Formula Parent Hydrocarbon Common name Carbinol name IUPAC name
CH3-OH Methane Methyl alcohol Carbinol Methanol
CH3-CH2-OH Ethane Ethyl alcohol Methyl carbinol Ethanol
CH3-CH(OH)-CH3 Propane Isopropyl alcohol Dimethyl carbinol 2-Propanol
(CH3)3-C-OH 2-Methyl propane Tert-butyl alcohol Trimethyl carbinol 2-Methyl-2-propanol

Ethanol is known as ethyl alcohol, grain alcohol and the spirit of wine. The first system of nomenclature for alcohol which was based on the use of the term “carbinol” for methanol was originated by a 19th-century German chemist Harmann Kolbe. The present accepted systematic nomenclature for alcohol was adopted by the International Union of Pure and Applied Chemistry in Paris in 1957.

Solved Example

Name the following compound.


This compound has a three-carbon chain, so the parent alkane name is propane. Because the compound contains three hydroxyl groups, the suffix must be -triol. Therefore, the name is 1,2,3-propanetriol.

The common name of this compound is glycerol is also called glycerin and it is an important by-product in the manufacture of soaps.

Test Your Knowledge On Nomenclature Of Alcohols!

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