Coordination Number

The Coordination number of an atom in a given molecule or a crystal refers to the total number of atoms, ion, or molecules bonded to the atom in question. ‘Ligancy’ is another term used to refer to the coordination number of an atom.

The atoms, ions, or molecules that are bonded to the central atom (or molecule/ion) are called ligands. The ligancy of molecules is calculated in a different manner when compared to calculating the coordination number of a central atom in a crystal.

Coordination Number of a Central Atom

In the case of polyatomic ions and molecules, the coordination number corresponding to a given atom can be calculated by counting the total number of atoms it is bonded to, be it a single bond or a double/triple bond.

Considering the example of the polyatomic ion given by the formula [Cr(NH3)2Cl2Br2], the coordination number of the central cation (Cr3+) can be counted by the total number of atoms bonded to the chromium atom, which is found to be 6.

Coordination Number

In the example provided above, it can be observed that the coordination number of the central cobalt atom is 6 since it is bonded to 6 different nitrogen atoms.

For crystals, the bonds are not as clear in their solid state structures. In such cases, the value of the coordination number of the central atom equals the total number of neighboring atoms to the atom in question.

The total number of neighboring atoms to a specific atom in a crystal depends on the location of the atom in the crystal. Therefore, there are 2 different measures for ligancy in the case of crystals, namely the bulk coordination number and the surface coordination number.

In the case of coordination complexes, only the sigma bonds between the ligands and the central atom are counted in the calculation of the coordination number of the central atom. Pi bonds are disregarded in this calculation.

For example, in the compound tungsten hexacarbonyl, given by the chemical formula W(CO)6,  the coordination number of the central tungsten atom (denoted by the symbol W) is 6 despite the importance of pi bonding along with sigma bonding in such metal carbonyls.

Geometry of Molecules Based on Coordination Number

There exist multiple possible geometric combinations for each value of the coordination number for the central atom. These possible geometric shapes are tabulated below.

Coordination Number Geometric Structure
2 Linear
3 Trigonal planar, T-shaped, or trigonal pyramidal
4 Square planar or tetrahedral
5 Trigonal bipyramidal or square pyramid structures
6 Trigonal prism structure, hexagonal planar, or octahedral
7 Pentagonal bipyramidal, capped octahedron, or a capped trigonal prism structure.
8 Cubic, hexagonal bipyramidal, square antiprism, or dodecahedron
9 Three-face centered trigonal prism
10 A bicapped square antiprism structure
11 All faced capped trigonal prism structure
12 Cuboctahedron structure

Thus, the various geometric structures possible with different coordination numbers of a central atom are discussed. To learn more about this concept and other concepts related to coordination compounds, register with BYJU’S and download the mobile application on your smartphone.


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