Chromic Oxide - Cr2O3

What is Chromic oxide?

Cr2O3 is an inorganic compound with chemical name Chromic oxide. It is also called Dichromium trioxide, or Chromium (3+) oxide, or Chromium (III) oxide. It naturally occurs in a mineral eskolaite, which is mostly found in chromium-rich skarns, tremolite, chlorite veins, and meta quartzites. Chromium (III) oxide appears as a fine light to dark green, hexagonal crystal. It is amphoteric and insoluble in water.

Properties of Chromic oxide – Cr2O3

Cr2O3 Chromic oxide
Molecular weight of Cr2O3 151.9904 g/mol
Density of Chromic oxide 5.22 g/cm3
Boiling point of Chromic oxide 4,000 °C
Melting point of Chromic oxide 2,435 °C

Chromic oxide structure – Cr2O3

Structure of Chromic oxide

The exact mass and the monoisotopic mass of Chromium (3+) oxide is 151.866 g/mol. The number of hydrogen bond acceptors equals to three and the number of hydrogen bond donors equals to zero. This compound is canonicalized and has five covalently bonded unit.

Cr2O3 Uses (Chromic oxide)

  • Chromic oxide is used in electric semiconductors.
  • Used in the colouring glass.
  • Used in promoting senescence.
  • Used in dyeing polymers.
  • Used in the manufacturing of chromium metal.
  • Used as a catalyst to prepare butadiene.
  • Used in stainless steel polishing.
  • Used as an anaesthetic.
  • Used to add colours in drugs.
  • Used in welding metals.

Production of Chromic oxide

In the year 1838, the Parisians Pannetier and Binet prepared the transparent hydrated form of Chromium (III) oxide. It is obtained from the mineral chromite. The conversion of chromite to chromia is as follows:

Na2Cr2O7 + S → Na2SO4 + Cr2O3

The oxide can also be made by decomposing chromium salts or by exothermically decomposing ammonium dichromate.

(NH4)2Cr2O7 → Cr2O3 + N2 + 4 H2O

Chemical reactions:

Dichromium trioxide when heated with finely divided aluminium or carbon reduces to chromium metal. The reaction is as follows:

Cr2O3 + 2Al → 2Cr + Al2O3

Heating Chromium (III) oxide with carbon and chlorine gives CrCl3 and carbon monoxide (CO):

Cr2O3 + 3Cl2 + 3C → 2CrCl3 + 3CO

Oxidation of chromium (III) oxide results in chromates:

2Cr2O3 + 4MO + 3O2 → 4MCrO4

Learn more about the Structure, physical and chemical properties of Cr2O3 from the experts at BYJU’S.

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