Chemical Equilibrium Formulas For Neet

When the system consists of more than one substance and the composition of the system does not vary with time, the system is said to be in chemical equilibrium. The chemical composition of a system at equilibrium must be uniform and there should be no net chemical reaction taking place.

Types of Reaction

  1. Reversible reaction
  2. Irreversible reaction

State of Equilibrium

Most of the chemical reactions do not go to completion in a closed system and attain a state of equilibrium.

Another approach comes from kinetics as developed by Guldberg and Waage (1863). Equilibrium is said to have reached a physical or chemical system when the rate of forward and reverse processes are equal.

At equilibrium,

Rate of forward reaction = Rate of backward reaction

Law of Chemical Equilibrium or Mass Action

At equilibrium,

rf = rb

Law of Chemical Equilibrium

Where Kc = kf / kb

Where [ ] is used to indicate “molar concentration”.

Equilibrium Constant in terms of Partial Pressure

In a gaseous system, we can use partial pressure terms in places of active masses. Thus, for the above gaseous equilibrium,

Equilibrium Constant

Where, Kp is equilibrium constant in terms of partial pressure.

Equilibrium Constant in terms of Mole Fraction

Mole Fraction

Where Kx is the equilibrium constant in terms of mole fraction.

Relation between Kp and Kc

Kp = Kc (RT)Δn

where R is gas constant 0.0821 liter.atm/degree/mole and Δn is total number of molecules of the product – total number of molecules of the reactants.

Relation between Equilibrium Constant and Standard Free Energy

ΔGo = – RT ln Keq

(or)

ΔGo = – 2.303RT log Keq

Reaction Quotient (Q)

The reaction quotient has the same algebraic form as Keq but the current concentrations nor specifically the equilibrium concentrations are used in calculations.

The expression for Q is

Reaction Quotient (Q)

Degree of Dissociation

Degree of dissociation (ɑ) = No. of molecules dissociated/Total no.of molecules taken.

Dissociation constant, Kdiss

Degree of Dissociation

Factors affecting Equilibrium

Le-chatelier’s Principle

If an equilibrium system is subjected to a change of any one of the factors such as temperature, pressure or concentration the equilibrium shifts in the direction that ends the annual effect of that change.

Important conclusion of the principle are

Pressure change

The increase of pressure of an equilibrium system shifts the equilibrium in the direction in which there is a decrease in volume.

Temperature change

The increase of temperature favours the reaction which takes place with an absorption of heat. The effect of decrease in temperature is just the reverse of it.

Concentration

When a substance is added its active mass increases. Hence the reaction will proceed in the direction in which the increase in active mass is used up.

Effect of adding an inert gas

At constant volume equilibrium is unaffected. At constant pressure, the volume of the system increases.

Thermodynamics of Equilibrium

Van’t Hoff Equation =

Thermodynamics of Equilibrium

(or)

Thermodynamics of Equilibrium1

Chemical equilibrium is the stage of a reversible reaction at which the active masses of the reactants and the products become constant in mixture and do not change with time. It is the state of a reversible reaction at which measurable properties like colour, density, pressure and concentration are nearly unchangeable.

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