Balancing redox reactions can become quite complicated and a systematic approach should be used. The half-reaction method of balancing redox reactions emphasizes the fact that redox reactions can be separated into an oxidation half-reaction, which shows only the oxidation process and a reduction half-reactions which shows the reduction process. For the overall balanced reaction, the two half-reactions are combined so that the electrons in the two half-reactions cancel. The half-reaction method is particularly useful for reactions in aqueous solution. The two half-reactions are combined to make a balanced redox equation.

1. Which of the following represents a redox reaction?

  1. NaOH + HCl → NaCl + H2O
  2. BaCl2 + H2SO4 → BaSO4 + 2HCl
  3. CuSO4 + 2H2O → Cu(OH)2 + H2SO3
  4. Zn + 2HCl → ZnCl2 + H2

Answer: (d)

2. Which reaction involves neither oxidation nor reduction?

  1. CrO42- -→ Cr2O72-
  2. Cr → CrCl3
  3. Na → Na+
  4. 2S2O32- → S4O62-

Answer: (a)

3. Zn gives H2 gas with H2SO4 and HCl but not with HNO3 because

  1. Zn acts as an oxidising agent when it reacts with HNO3
  2. HNO3 is a weaker acid than H2SO4 and HCl
  3. In electrochemical series, Zn is above hydrogen
  4. NO3– is reduced in preference to hydronium ion

Answer: (d)

4. A compound of Xe and F is found to have 53.5% of Xe. What is the oxidation number of Xe in this compound?

  1. -4
  2. 0
  3. +4
  4. +6

Answer: (d)

5. A solution contains Fe2+, Fe3+ and I– ions. This solution was treated with iodine at 35oC. Eo for Fe3+/Fe2+ is 0.77V and Eo for I2/2I– = 0.536V. The favourable redox reaction is

  1. I2 will be reduced to I–
  2. there will be no redox reaction
  3. I– will be oxidised to I2
  4. Fe2+ will be oxidised to Fe3+

Answer: (c)

6. One mole of N2H4 loses 10 moles of electrons to form a new compound y. Assuming that all nitrogen appears in the new compound, what is the oxidation state of nitrogen in y.

  1. -1
  2. -3
  3. +3
  4. +5

Answer: (c)

7. The equivalent mass of oxidising agent in the following reaction is

SO2 + 2H2S → 3S + 2H2O

  1. 32
  2. 64
  3. 16
  4. 8

Answer: (c)

8. In the reaction

3Br2 + 6CO32- + 3H2O → 5Br– + BrO3– + 6HCO3–

  1. bromine is oxidised and carbonate is reduced
  2. bromine is reduced and water is oxidised
  3. bromine is neither reduced nor oxidised
  4. bromine is both reduced and oxidised

Answer: (d)

9. Which of the following cannot function as an oxidising agent?

  1. I–
  2. Si(s)
  3. NO3–(aq)
  4. Cr2O72-

Answer: (a)

10. The oxidation number of Pt in [Pt(C2H4)Cl3]– is

  1. +1
  2. +2
  3. +3
  4. +4

Answer: (b)

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