NEET 2023 is approaching, and it is time to do thorough revisions and give your best for the entrance exam. We often overlook the most important questions in Organic Chemistry while reading the theory. This comprehensive session has provided you with the most important questions of Complete Organic Chemistry for NEET 2023.
Question 1: The IUPAC name of the following compound is ________. (CH3)2CHโCH2CH=CHโCH=CHโCHCH3โC2H5
- 1, 1, 7, 7-tetramethyl-2, 5-octadiene
- 2, 8-dimethyl-3, 6-decadiene
- 1, 5-diisopropyl-1, 4-hexadiene
- 2, 8-dimethyl-4, 6-decadiene
Answer: (d) 2, 8-dimethyl-4, 6-decadiene
Explanation: Identification of parent chain: First, determine which carbon chain in the molecule is the longest. The longest chain in the given compound has ten carbons and is referred to as the parent or root chain.
Assign numbers to the parent chain: The functional group is connected to the carbon atom with the lowest possible number in the longest chain of carbon atoms carrying the functional group.
The C=C functional groups are found at carbon atoms 4 and 6, while the substituent (โCH3) is present at carbon atoms 2 and 8. The C=C functional groups are indicated by the suffixes ‘ene’.
Hence, the name of the compound is 2, 8-dimethyl-4, 6-decadiene.
Question 2: The most stable carbanion among the following is __________.
Answer: (d)
Explanation: Dispersion of โve charge by โM and โI group stabilises the carbanions. NO2 group on benzene stabilises the carbanion.
Question 3: Which of the following phenols has the largest pKa value?
Answer: (c)
Explanation: Acidic strength โ Ka โ 1/pKa
The presence of an electron-withdrawing group makes phenol more acidic because it stabilises the phenoxide ion generated when the proton is removed. Electron-donating groups, on the other hand, reduce the acidic intensity of phenol.
As a result, pโmethyl phenol will have the least acidity and the highest pKa value.
Question 4: Which of the following has inductive, mesomeric, and hyperconjugation effects?
- CH3Cl
- CH3โCH=CH2
- CH3โCH=CHโCOโCH3
- CH2=CHโCH=CH2
Answer: (c) CH3โCH=CHโCOโCH3
Explanation: Because of the carbonyl group, double bond resonance alpha hydrogens are also present, due to which hyperconjugation occurs.
Question 5: The correct stability order for the following species is _________.
- II > IV > I > III
- I > II > III > IV
- II > I > IV > III
- I > III > II > IV
Answer: (d) I > III > II > IV
Explanation:
The lone pair on oxygen stabilises the carbocation in the Ist option, making it more stable than the tertiary carbocation.
The stability of carbocations should be in the order: tertiary alkyl > secondary alkyl > primary alkyl > methyl carbonium ion.
The stability of a carbocation increases when an electron donating group (+I effect) is present.
Question 6: Which among the given molecules can exhibit tautomerism?
- Both I and II
- Both II and III
- III only
- Both I and III
Answer: (c) III only
Explanation:
ฮฑ-Hydrogen at bridge carbon does not ever participate in tautomerism. Thus, only (III) exhibits tautomerism.
Question 7: What is the total number of structural isomers C4H10O?
- 7
- 5
- 4
- 6
Answer: (a) 7
Explanation: C4H10O will have seven structural isomers, four of which will be alcohols and three of which will be ethers.
- n-butanol
- butan-2-ol
- 2-methyl-propanol
- 2-methyl propane-2-ol
- diethyl ether
- 1-methoxy propane
- 2-methoxy propane
As a result, 7 is the right answer.
Question 8: For the given reaction, what is โAโ?
Answer: (c)
Question 9: An unsaturated hydrocarbon โXโ on ozonolysis gives โAโ. Compound A when warmed with ammoniacal silver nitrate, forms a bright silver mirror along the sides of the test tube. The unsaturated hydrocarbon X is _________.
Answer: (c)
Question 10: The compound which reacts faster in the SN2 mechanism is _________.
- CH3CโCl
- H2C=CHโCl
- H2C=CHโCH2โCl
- C6H5โCH2โBr
Anwer: (c) H2C=CHโCH2โCl
Explanation: H2C=CHโCH2โCl will easily participate in the Substitution reaction. Hence, it reacts faster in SN2 mechanism as it is primary and has less stearic hindrance.
Question 11: The product โAโ in the given reaction is __________.
Answer: (b)
Question 12: 3-Methylpent-2-ene on reaction with HBr in the presence of peroxide forms an additional product. The number of possible stereoisomers for the product is _________.
- Six
- Three
- Two
- Four
Answer: (d) Four
Since the product (X) includes 2 chiral centres, it is asymmetrical.
As a result, the total stereoisomers are 22 = 4.
Question 13: The most suitable reagent for the given conversion is __________.
RโCH2OH โ RโCHO
- PCC
- KMnO4
- K2Cr2O7
- Anhydrous CrO3
Answer: (a) PCC
Explanation: RโCH2OH โ RโCHO is an oxidation reaction.
Pyridinium chlorochromate (PCC) is a mild oxidising agent that converts primary and secondary alcohols to aldehydes and ketones, respectively. It has a great selectivity for oxidation of alcohols because it has no effect on any other functional group. Acidic permanganate, acidic dichromate, and chromic anhydride in glacial acetic acid are strong oxidising agents that can further oxidise and produce carboxylic acid.
The most suitable reagent for RโCH2OH โ RโCHO is pyridinium chlorochromate (PCC)
Question 14: Match the chemical conversions in List I with appropriate events in List II and select the correct answer using the code given.
Answer: (a)
Question 15: In the given transformation, which of the following is the most appropriate reagent?
- Zn(Hg)-HCl
- Na, Liq.NH3
- NaBH4
- NH2NH2,OHโ
Answer: (d) NH2NH2,OHโ
Explanation: The OH group attached to the compound is unaffected by the Wolff Kishner reaction.
Question 16: The number of aldol reaction(s) that occur in the given transformation is _______.
- 1
- 2
- 3
- 4
Answer: (c) 3
Explanation:
Due to the presence of ฮฑโH in steps 1, 2, and 3, an aldol addition reaction occurs. Because ฮฑโH isn’t present, step 4 is a Cannizzaro reaction.
Question 17: The total number of amines among the following that can be synthesised by Gabriel synthesis is __________.
- 1
- 2
- 3
- 4
Answer: (c) 3
Explanation: A total of 3 amines can be synthesised by Gabriel synthesis. The Gabriel phthalimide synthesis is commonly used to produce 1ยฐ aliphatic/alicyclic amine. As a result, the amine that can be synthesised using the Gabriel Phthalimide synthesis technique is (A) Me2CH-CH2-NH2 (B) CH3CH2NH2 (C) ph-CH2-NH2
Question 18: Match List I with List II.
List I | List II |
P) Sucrose | 1) ฮฒ-D-Galactose and ฮฒ-D-Glucose |
Q) Lactose | 2) ฮฑ-D-Glucose and ฮฒ-D-Fructose |
R) Maltose | 3) ฮฑ-D-Glucose and ฮฑ-D-Glucose |
- 3,2,1
- 3,1,2
- 1,3,2
- 2,1,3
Answer: (d) 2,1,3
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