Diborane

Diborane is a chemical compound that consists of boron and hydrogen atoms and has a molecular formula B2H6. This substance is highly unstable at the room temperature with a sweet odour. The compounds consisting of boron and hydrogen atoms are called boranes. Diborane is one of the simplest boron hydrides.

The Boron hydrides mix well with the air forming up explosive mixtures. This substance will ignite rapidly at room temperature. The other names for Diborane are boro ethane, diboron hexahydride.

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Structure Of Diborane

Diborane

The structure of Diborane molecule consists of four hydrogen atoms and that of two boron atoms coming on the same plane. In between these planes, there are said to be two dividing atoms of hydrogen.

The boron atom is known to be sp3 hybridized and has four hybrid orbitals. From these four hybrid orbitals, three of the orbitals have one electron each, and of which one is an empty orbital. The two electrons of the hybrid orbitals in each of the boron atoms form 2 bonds with the 1s hydrogen atoms. The two atoms of boron left with that of each unpaired electron orbital and empty orbital forms the two bridgings (B–H–B) bonds with that of the two 1s hydrogen atoms, is also called as the banana bond.

Properties Of Diborane

Some of the physical and chemical properties of Diborane are as below:

  • Diborane is said to be a colourless and highly flammable type of gas at the room temperatures. At the high concentrations, it ignites rapidly in the presence of moist air at the room temperature.
  • It smells sweet.
  • It is said to have a boiling point of about 180 K and is a toxic gas.
  • It releases a huge amount of energy when burnt in the presence of oxygen.
  • Diborane readily hydrolyzes in water to give hydrogen gas and boric acid.
  • Most of the diborane are known to be flammable in air.

Preparation Of Diborane

The action of a metal hydride with boron produced diborane. This approach is common in the industrial production of diborane.

The reaction of iodine with sodium borohydride in diglyme can also produce diborane in small quantities.

2NaBH4 + I2  → B2H6  + 2NaI + H2 

On heating magnesium boride with HCl, a mixture of volatile boranes is obtained.

2Mg3B2  + 12HCl → 6MgCl2 + B4H10 + H2

B4H10 + H2 → 2B2H6

Reactions

– Pure diborane does not react with air or oxygen at room temperature, but it gives B2O3 together with large amounts of energy in impure form.

B2H6 + 3O2  → B2O3 + 3H2O

ΔH = -2165 KJ mol-1

– Diborane reacts with methyl alcohol to give trimethyl Borate.

B2H6 + 6CH3OH  → 2B(OCH3)3 + 6H2

– Reaction with ionic hydrides

It forms metal borohydrides when treated with metal hydrides

– Reaction with ammonia

Diborane is given when treated with excess ammonia at low temperatures. It gives borazole when heated at higher temperatures.

Hydroboration

 The ether solvent, Diborane adds alkenes and alkynes at room temperature. This reaction is called hydroboration and is commonly used in synthetic organic chemistry, especially for the addition of anti-Markovnikov.

B2H6 + 6RCH=CHR → 2B(RCH-CH2R)3

Uses And Applications Of Diborane

Diborane is a chemical substance has many numbers of applications in various fields, of which some are given below:

  • Diborane is used as a rocket propellant.
  • It is utilized in the manufacture of borophosphosilicate which is a form of glass.
  • In most of the chemical reactions, it is employed as a reducing agent.
  • Diborane is used as a catalyst and rubber vulcanizer in the polymerization reactions.
  • It is even used as a doping agent in the manufacturing of semiconductor devices.

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