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Isochoric Process

What Is the Isochoric Process?

A thermodynamic process taking place at constant volume is known as the isochoric process. It is also called an isometric process or constant-volume process. The term isochoric has been derived from the Greek words “iso” meaning “constant” or “equal”, and “choric”, meaning “space” or “volume.”

An isochoric process is one for which,

\(\begin{array}{l}{{V}_{f}}={{V}_{i}}\,\,\,\,\,\,\,\,\,\left( \Delta \upsilon = 0,d\upsilon = 0 \right)\end{array} \)

In such a process, the work done is zero (since dW = P dV = 0 when V = constant). Hence, from the first law of thermodynamics,

dQ = dU (isochoric process)

The total heat supplied or rejected is also equal to the increase or decrease in the internal energy of the system.

Isochoric Process Example

A good example of an isochoric process is the ideal Otto cycle. In this, when the gasoline-air mixture is burnt in a car’s engine, there is an increase in the temperature and the pressure of the gas inside the engine. On the other hand, the volume of the gas remains exactly the same.

Also Read:

Isothermal Process
Isobaric Process
Adiabatic Process

Work Done by a Gas in an Isochoric Process

In an isochoric process, the volume of the gas remains constant. For example, suppose you have an ideal gas in a closed rigid container; heating the gas will raise its pressure without changing its volume. However, the quantity of gas remains constant. We can further deduce that the increase in energy is proportional to an increase in pressure and temperature.

This is represented by a vertical line on a P-V diagram. Since the volume does not change,

Isochoric process P – V diagram

 

 

\(\begin{array}{l}dV=0\end{array} \)

 

\(\begin{array}{l}W=\int_{{{V}_{i}}}^{{{V}_{f}}}{PdV=0}\end{array} \)

Whether the pressure change is positive or negative, the work done by the gas in an isochoric process is zero.

Work done by a gas in a process in which PVn = constant, where n is also constant.

Also Read: Thermodynamics

Frequently Asked Questions (FAQs)

Q1

What is meant by an isochoric process?

An isochoric process is a process that takes place at constant volume.
Q2

What is the value of ΔV during the isochoric process?

The value of ΔV = 0 in an isochoric process.
Q3

What is the value of work done by an ideal gas during the isochoric process?

The work done by an ideal gas during an isochoric process is zero.
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