Gas laws are those laws which describe the properties of gases with respect to temperature, moles, volume and pressure. The laws related to all these properties and help in the approximation for most of the gases. In normal condition all gasses shows similar behaviour, variation occurs when the physical parameters such as temperature, pressure and volumes are slightly altered. The law basically describes the deviations in the behaviour of gases. The gas laws were formulated at the end of the 18th century and were a result of many different science experiments.
There are many several types of gas laws, proposed by different scientists in different periods. While the laws have been named after the scientist who discovered it. The important thing to be aware of here is to understand the relationship between the different laws.
We will look at all the gas laws below and also understand a few underlying topics.
- Boyle’s law
- Charle’s law
- Gay-Lussac law
- Avogadro’s law
- Combined Gas law
- Combined Gas law
- Gas Law Table
- Gas Law Problems
- Applications of Gas Law
Boyle’s law gives the relationship between the pressure of a gas and volume of the gas at a constant temperature. Basically, the volume of a gas is inversely proportional to the pressure of a gas at a constant temperature.
Boyle’s law equation is written as:
V ∝ 1/P
P ∝ 1/V
PV = k1
Where V is the volume of the gas, P is the pressure of the gas and K1 is the constant. Boyle’s Law can be used to determine the current pressure or volume of gas and can be represented also as;
P1V1 = P2V2
Boyle’s Law-Related Problem
An 18.10mL sample of gas is at 3.500 atm. What will be the volume if the pressure becomes 2.500 atm, with a fixed amount of gas and temperature?
By solving with the help of Boyle’s law equation
P1V1 = P2V2
V2 = P1V1 / P2
V2 = (18.10 * 3.500atm)/2.500atm
V2 = 25.34 mL
Also Read: Behaviour of Gases
Charle’s law states that at constant pressure, the volume of a gas is directly proportional to the temperature (in Kelvin) in a closed system. Basically, this law describes the relationship between the temperature and volume of the gas.
Mathematically, Charle’s law can be expressed as;
V ∝ T
Where, V = volume of gas, T = temperature of the gas in Kelvin. Another form of this equation can be written as;
V1 / T1 = V2 / T2
Charle’s law problem
A sample of Carbon dioxide in a pump has a volume of 21.5 mL and it is at 50.0 oC. When the amount of gas and pressure remain constant, find the new volume of Carbon dioxide in the pump if the temperature is increased to 75.0 oC.
V2 = V1T2/T1
V2 = 7,485.225/ 323.15
V2 = 23.16 mL
Gay-Lussac law gives the relationship between temperature and pressure at constant volume. The law states that at a constant volume, the pressure of the gas is directly proportional to the temperature for a given gas.
If you heat up a gas, the molecules will be given more energy so they move faster. If you cool down the molecules, they slow down and the pressure decreases. The change in temperature and pressure can be calculated using Gay-Lussac law and it is mathematically represented as;
P ∝ T
P / T = k1
P1 / T1 = P2 / T2
Where P is the pressure of the gas and T is the temperature of the gas in Kelvin.
Gay-Lussac Law related problem
Determine the pressure change when a constant volume of gas at 2.00 atm is heated from 30.0 °C to 40.0 °C.
P1T1 = P2T2
P2 = 626.3/303.15
P2 = 2.0659
Avogadro’s law states that if the gas is an ideal gas, the same number of molecules exists in the system. The law also states that if the volume of gases is equal it means that the number of the molecule will be the same as the ideal gas only when it has equal volume. This above statement can be mathematically expressed as;
V / n = constant
V1 / n1 = V2 / n2
Where V is the volume of an ideal gas and n in the above equation represent the number of gas molecules.
Problems related to Avogadro’s Law
At constant temperature and pressure, 6.00 L of a gas is known to contain 0.975 mol. If the amount of gas is increased to 1.90 mol, what new volume will result?
V1n1 = V2n2
V2 = (6*1.90)/0.975
Combined Gas Law
The combined gas law is also known as a general gas equation is obtained by combining three gas laws which include Charle’s law, Boyle’s Law and Gay-Lussac law. The law shows the relationship between temperature, volume and pressure for a fixed quantity of gas.
The general equation of combined gas law is given as;
PV / T = k
If we want to compare the same gas in different cases, the law can be represented as;
P1V1 / T1 = P2V2 / T2
Also Read: Kinetic Theory of Gas
Ideal Gas Law
Much like the combined gas law, the ideal gas law is also an amalgamation of four different gas laws. Here, Avogadro’s law is added and the combined gas law is converted into the ideal gas law. This law relates four different variables which are pressure, volume, no of moles or molecules and temperature. Basically, the ideal gas law gives the relationship between these above four different variables.
Mathematically Ideal gas law is expressed as;
V = volume of gas.
T = temperature of the gas.
P = pressure of the gas.
R = universal gas constant.
n denotes the number of moles.
We can also use an equivalent equation given below.
PV = kNT
Where, k = Boltzman constant and N = number of gas molecules.
Ideal gases are also known as a perfect gas. It establishes a relationship among the four different gas variables such as pressure (P), Volume(V), Temperature(T) and amount of gas (n).
Ideal Gas Properties and Characteristics
- The motion of ideal gas in a straight line constant and random.
- The gas occupies a very small space because the particle in the gas is extremely small.
- There is no force present between the particle of the gas. Particles only collide elastically with the walls of the container and with each other.
- The average kinetic energy of the gas-particle is directly proportional to the absolute temperature.
- The gases are made up of a large number of same particles (atoms or molecules) which are perfectly hard spheres and also very small in size.
- The actual volume of the gas molecule is considered negligible as compared to the space between them and because of this reason they are considered as the point masses.
Gas Law Formula Table
The following table consists of all the formulas of Gas Law.
|Charle’s Law||V1/T1=V2/T2||At constant P, as the volume increases the temperature also increases.|
|Boyle’s Law||P1V1=P2V2||At constant T, if pressure increases then volume decreases.|
|Gay- Lussac Law||P1/T1=P2/T2||At constant V as pressure increases the temperature also increases.|
|Avogadro’s Law||V / n = constant||When the amount of gas increases, the volume of the gas also increases.|
|Ideal Gas Law||PV=nRT|
Gas Law Problems
A sealed jar whose volume is exactly 1L which contains 1 mole of air at temperature 20-degree Celcius, assuming that the air behaves as an ideal gas. So what is the pressure inside the jar in Pa?
By solving with the help of ideal gas equation
(1) By rearranging the equation we can get,
(2) Write down all the values which are known in S.I unit
T= 20degree celcius=(20+273.15)K=293.15K
(3) Put all the values in the equation
Application Of Gas-law
During summer when the temperature is high and pressure is also high, a tire is at risk of bursting because it is inflated with air. Or when you start climbing a mountain you feel some problems related to inhaling? Why does it happen?
When the physical condition is changing with changing in the environment the behaviour of gases particle also deviates from there normal behaviour. These changes in gas behaviour can be studied by studying various laws known as gas law.
The gas laws have been around for quite some time now and they significantly assist scientists in finding amounts, pressure, volume, and temperature when coming to matters of gas.
Besides, the gas law along with modern forms are used in many practical applications that concern a gas. For example, respiratory gas measurement of tidal volume and vital capacity etc are done at ambient temperature while these exchanges actually take place in the body at 37-degree Celcius. The law is also used often in thermodynamics as well as in fluid dynamics. It can be used in the weather forecast systems.