What Is Solubility?
Solubility is the amount of the substance (ionic or others) soluble to make a saturated solution at a specified temperature and in a fixed volume of solvent. Solubility changes with the nature of the substance, solvent, temperature and presence of common ions.
Sparingly soluble substances have very low solubility (AgCl, BaSO4) in water. In spite of the low solubility, being ionic substances, they can be considered to form a saturated solution, and the ions are in equilibrium with the undissolved solid.
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(Undissolved ) (Dissolved)
Equilibrium constant of dissociation
Silver chloride being solid, the concentration is taken to be constant, such that a new equilibrium constant can be considered.
For a sparingly insoluble salt of the general formula, AxBy
The value is constant for the substance and varies only with temperature.
Significance of Solubility Product
- The presence of a common ion may affect the equilibrium and hence, the concentration (solubility) but not the solubility product.
- Precipitation of the solutes occurs when the ionic product exceeds the Ksp.
Solubility – JEE Chemistry
Solubility and Henry’s Law
Relationship between Solubility and Solubility Product
At equilibrium C Cx Cy
Ksp = [xAY+ ]x[yBx-]y = [Cx]x [Cy]y = [C]x [x]x [C]y [y]y
Ksp = [C]x [C]y [x]x [y]y = [C]x+y [x]x [y]y
Ksp = [S]x+y [x]x [y]y S is the solubility= C= mole/l
Example: For silver chromate,
Ksp = (2S)2 S = 4S3