Hybridization

Hybridization is defined as the concept of mixing two atomic orbitals with the same energy levels to give a degenerated new type of orbitals. This intermixing is based on quantum mechanics. The atomic orbitals of the same energy level can only take part in hybridization and both full filled and half-filled orbitals can also take part in this process provided they have equal energy.

During the process of hybridization, the atomic orbitals of similar energy are mixed together such as the mixing of two ‘s’ orbitals or two ‘p’ orbital’s or mixing of an ‘s’ orbital with a ‘p’ orbital or ‘s’ orbital with a ‘d’ orbital.

Table of Content

What is Hybridization?

Redistribution of the energy of orbitals of individual atoms to give orbitals of equivalent energy happens when two atomic orbitals combine together to form hybrid orbital in a molecule. This process is called hybridization. The new orbitals thus formed are known as hybrid orbitals.

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Types of Hybridization

Based on the types of orbitals involved in mixing, the hybridization can be classified as sp3, sp2, sp, sp3d, sp3d2, sp3d3. Let us now discuss the various types of hybridization along with their examples.

sp Hybridization

sp hybridization is observed when one s and one p orbital in the same main shell of an atom mix to form two new equivalent orbitals. The new orbitals formed are called sp hybridized orbitals. It forms linear molecules with an angle of 180°

  • This type of hybridization involves the mixing of one ‘s’ orbital and one ‘p’ orbital of equal energy to give a new hybrid orbital known as an sp hybridized orbital.
  • sp hybridization is also called diagonal hybridization.
  • Each sp hybridized orbital has an equal amount of s and p character, i.e., 50% s and p character.

sp Hybridization

Examples of sp Hybridization:

sp2 Hybridization

sp2 hybridisation is observed when one s and two p orbitals of the same shell of an atom mix to form 3 equivalent orbital. The new orbitals formed are called sp2 hybrid orbitals. 

  • sphybridization is also called trigonal hybridization.
  • It involves mixing of one ‘s’ orbital and two ‘p’ orbital’s of equal energy to give a new hybrid orbital known as sp2.
  • A mixture of s and p orbital formed in trigonal symmetry and is maintained at 1200.
  • All the three hybrid orbitals remain in one plane and make an angle of 120° with one another. Each of the hybrid orbitals formed has 33.33% s character and 66.66% ‘p’ character.
  • The molecules in which the central atom is linked to 3 atoms and is sp2 hybridized have a triangular planar shape.

sp2 Hybridization

Examples of sp2 Hybridization

  • All the compounds of Boron i.e. BF3, BH3
  • All the compounds of carbon containing a carbon-carbon double bond, Ethylene (C2H4)

sp3 Hybridization

When one ‘s’ orbital and 3 ‘p’ orbitals belonging to the same shell of an atom mix together to form four new equivalent orbital, the type of hybridization is called a tetrahedral hybridization or sp3. The new orbitals formed are called sp3 hybrid orbitals.

  • These are directed towards the four corners of a regular tetrahedron and make an angle of 109°28’ with one another.
  •  The angle between the sp3 hybrid orbitals is 109.280
  • Each sp3 hybrid orbital has 25% s character and 75% p character.
  • Example of sp3 hybridization: ethane (C2H6), methane.

sp3 Hybridization

sp3d Hybridization

sp3d hybridization involves the mixing of 3p orbitals and 1d orbital to form 5 sp3d hybridized orbitals of equal energy. They have trigonal bipyramidal geometry.

  • The mixture of s, p and d orbital forms trigonal bipyramidal symmetry.
  • Three hybrid orbitals lie in the horizontal plane inclined at an angle of 120° to each other known as the equatorial orbitals.
  • The remaining two orbitals lie in the vertical plane at 90 degrees plane of the equatorial orbitals known as axial orbitals.
  • Example: Hybridization in Phosphorus pentachloride (PCl5)

sp3d Hybridization

sp3dHybridization

  • sp3d2 hybridization has 1s, 3p and 2d orbitals, that undergo intermixing to form 6 identical sp3d2 hybrid orbitals.
  • These 6 orbitals are directed towards the corners of an octahedron.
  • They are inclined at an angle of 90 degrees to one another.

Key Features of Hybridization

  • Atomic orbitals with equal energies undergo hybridization.
  • The number of hybrid orbitals formed is equal to the number of atomic orbitals mixing.
  • It is not necessary that all the half-filled orbitals must participate in hybridization. Even completely filled orbitals with slightly different energies can also participate.
  • Hybridization happens only during the bond formation and not in an isolated gaseous atom.
  • The shape of the molecule can be predicted if hybridization of the molecule is known.
  • The bigger lobe of the hybrid orbital always has a positive sign while the smaller lobe on the opposite side has a negative sign.

Try This: Give the hybridization states of each of the carbon atom in the given molecule.

  • H2C = CH – CN
  • HC ≡ C − C ≡ CH
  • H2C = C = C = CH2

Frequently Asked Questions on Hybridization

What are the different types of hybridization?

Based on the nature of the mixing orbitals, the hybridization can be classified as,

  • sp hybridization (beryllium chloride, acetylene)
  • sp2 hybridization (boron trichloride, ethylene)
  • sp3 hybridization (methane, ethane)
  • sp3d hybridization (phosphorus pentachloride)
  • sp3d2 hybridization (sulfur hexafluoride)
  • sp3d3 hybridization (iodine heptafluoride)

⇒ Know more about VSEPR theory its postulates and limitations

Among sp, sp2 and sp3, which hybrid orbital is more electronegative?

The percentage of s character in sp, sp2, and sp3 hybridized carbon is 50%, 33.33%, and 25% respectively.

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Due to the spherical shape of s orbital, it is attracted evenly by the nucleus from all directions. Therefore, a hybrid orbital with more s-character will be closer to the nucleus and thus more electronegative. Hence, the sp hybridized carbon is more electronegative than sp2 and sp3.

Why the hybrid orbital during hybridization is better than their parent atoms?

The reason why a hybrid orbital is better than their parents:

  • Parent s: because it is directional unlike the s orbital.
  • Parent p: because it has lower energy than p orbital.

What are hybrid orbitals?

The hybrid orbitals can be defined as the combination of standard atomic orbitals resulting in the formation of new atomic orbitals.

⇒ Check: Fajan’s Rule and its Postulates

During hybridization, the hybrid orbitals possess different geometry of orbital arrangement and energies than the standard atomic orbitals. Also, the orbital overlap minimizes the energy of the molecule. The degenerate hybrid orbitals formed from the standard atomic orbitals:

  • 1s and 1 p: sp orbitals
  • 1s and 2p: sp2 orbitals
  • 1s and 3p: sp3 orbitals
  • 1s, 3p, and 1d: sp3d orbitals
  • 1s, 3p, and 2d: sp3d2 orbitals

What is the difference between sp, sp2 and sp3 hybridization?

sp hybridization occurs due to the mixing of one s and one p atomic orbital, sp2 hybridization is the mixing of one s and two p atomic orbitals and sp3 hybridization is the mixing of one s and three p atomic orbitals.

What is the percentage of s and p character in sp, sp2 and sp3 hybrid orbital?

The percentage of s and p character in sp, sp2 and sp3 hybrid orbital is,

Sp: s characteristic 50% and p characteristic 50%,

Sp2: s characteristic 33.33% and p characteristic 66.66%,

Sp3: s characteristic 25% and p characteristic 75%.

Explain the five basic shapes of Hybridization.

The five basic shapes of hybridization are linear, trigonal planar, tetrahedral, trigonal bipyramidal, and octahedral.

The geometry of the orbital arrangement:

  • Linear: Two electron groups involved resulting in sp hybridization, the angle between the orbitals is 180°.
  • Trigonal planar: Three electron groups involved resulting in sp2 hybridization, the angle between the orbitals is 120°.
  • Tetrahedral: Four electron groups involved resulting in sp3 hybridization, the angle between the orbitals is 109.5°.
  • Trigonal bipyramidal: Five electron groups involved resulting in sp3d hybridization, the angle between the orbitals is 90°, 120°.
  • Octahedral: Six electron groups involved resulting in sp3d2 hybridization, the angle between the orbitals is 90°.

Explain sp3 Hybridization in Methane

The 2s and all the three (3p) orbitals of carbon hybridize to form four sp3 orbitals. These hybrid orbitals bond with four atoms of hydrogen through sp3-s orbital overlap resulting in CH4 (methane). The geometry of orbital arrangement due to the minimum electron repulsion is tetrahedral.

Amide molecule looks sp3 hybridized but it is sp2, why?

The general process of hybridization will change if the atom is either enclosed by two or more p orbitals or it has a lone pair to jump into a p orbital. Therefore, in the case of amide molecule, the lone pair goes into a p orbital to have 3 adjacent parallel p orbitals (conjugation).

What results in sp, sp2 and sp3 hybridization?

Sp and sp2 hybridization results in two and one unhybridized p orbitals respectively whereas in sp3 hybridization there are no unhybridized p orbitals.

Explain the difference between molecular and hybrid orbitals?

The interactions between the atomic orbitals of two different atoms result in molecular orbitals whereas when the atomic orbitals of the same atom interact they form hybrid orbitals.

Practise This Question

Hybridization of sulphur in sulphur dioxide is

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